| Urea | 46% N | Amide nitrogen, converted to ammonium and then nitrate in soil | High when kept dry | Surface-applied granules can lose nitrogen as ammonia, especially on alkaline, warm, moist soils without rainfall or incorporation | Use a urease inhibitor such as NBPT or incorporate the fertilizer into soil; apply before forecast rainfall where appropriate | Pre-plant incorporation, banding, or application before reliable rainfall | Choose low-dust, uniform granules with controlled moisture and a documented inhibitor or coating performance |
| Ammonium Nitrate | Approximately 33–34% N | About half ammonium nitrogen and half nitrate nitrogen | Good if correctly stored | Nitrate is immediately mobile and can leach or denitrify; the material also requires strict oxidizer and heat-management controls | Use split applications, proper placement, and site-specific water management; follow applicable storage and safety regulations | Cool-season crops and situations requiring rapid nitrate availability | Evaluate regulatory status, storage controls, granule integrity, and nitrate-loss risk before purchase |
| Calcium Ammonium Nitrate | Approximately 26–28% N | Ammonium and nitrate nitrogen | Good | Nitrate remains vulnerable to leaching and denitrification; lower analysis means more product must be handled per unit of nitrogen | Use split applications and place nutrients close to the active root zone without overwatering | Top-dressing and applications where quick, reliable crop uptake is required | Useful when predictable field performance and lower ammonia-volatilization risk than surface urea are priorities |
| Ammonium Sulfate | Approximately 21% N | Ammonium nitrogen | High when kept dry | Ammonia losses can occur when left on the soil surface; repeated use may acidify soil over time | Incorporate or apply before rainfall; use soil pH and sulfur requirements to guide the rate | Soils or crops that also require sulfur, particularly where soil pH is not already low | Choose only when the sulfur value is agronomically justified and soil-acidity effects are monitored |
| UAN Solution | Common grades: 28–32% N | Urea, ammonium, and nitrate nitrogen in solution | Stable with temperature control | Crystallization may occur at low temperatures; surface application can cause ammonia loss, especially on residue-covered soil | Use a compatible urease inhibitor, maintain clean equipment, and select a grade with a suitable crystallization temperature for local conditions | Injection, banding, fertigation, and properly managed foliar or soil applications | Check freezing or crystallization behavior, compatibility with additives, tank-material requirements, and transport conditions |
| Urea with Urease Inhibitor | Usually close to the base urea analysis; verify the product label | Amide nitrogen with delayed urea hydrolysis | Depends on coating and handling | Inhibitor effectiveness can decline with storage, high temperature, moisture, or unsuitable blending; it does not eliminate nitrate leaching | Use a validated inhibitor rate and observe the stated treatment-to-application interval | Surface application where incorporation or rainfall cannot be reliably scheduled | Compare verified ammonia-loss reduction data, treatment uniformity, storage limits, and label directions—not only the inhibitor name |
| Nitrification-Inhibited Ammonium Fertilizer | Depends on the base fertilizer | Ammonium nitrogen with delayed conversion to nitrate | Depends on formulation | Performance varies with soil temperature, moisture, pH, microbial activity, and inhibitor placement | Use a registered nitrification inhibitor at the recommended rate and place it with or near the ammonium source | Wet soils, cool periods, or high-risk fields where nitrate leaching or denitrification is likely | Require independent or multi-location evidence under comparable soil, weather, and management conditions |
| Polymer-Coated Controlled-Release Urea | Often approximately 37–44% N, depending on coating level | Amide nitrogen released gradually through the coating | High if coating remains intact | Release rate changes with temperature, coating quality, physical damage, and placement; release may not match crop demand | Select a release pattern validated for the local temperature range and crop duration | Long-season crops, landscaped areas, and applications where fewer fertilizer events are preferred | Compare release curves, coating durability, temperature response, and residual material-management requirements |
| Liquid Ammonia | Approximately 82% N | Anhydrous ammonia, converted to ammonium in moist soil | Stable only under regulated conditions | Severe handling hazard; shallow or poorly sealed application can cause ammonia loss | Use trained operators, compliant equipment, sealed injection, and legally required storage and emergency procedures | Pre-plant or side-dress injection into suitable soil moisture conditions | Consider infrastructure, operator training, safety compliance, soil conditions, and total handling risk—not concentration alone |